Measured Data

Specific Heat

Experiments for specific heat [J/(kg K)], or heat capacity, were conducted using a heat flow meter on unconditioned and dried samples at 10 °C, 20 °C, 30 °C and 40 °C.

Unconditioned

Temperature (C) Specific Heat Mean (J/kg-K) Standard Deviation (J/kg-K)
10.0 1368.0 25.0
20.0 1437.0 32.0
30.0 1507.0 26.0
40.0 1578.0 33.0

Dried

Temperature (C) Specific Heat Mean (J/kg-K) Standard Deviation (J/kg-K)
10.0 1205.0 24.0
20.0 1253.0 18.0
30.0 1299.0 20.0
40.0 1354.0 38.0

Thermal Conductivity

Experiments for thermal conductivity [W/(m K)] were conducted using a heat flow meter on unconditioned and dried samples at 15 °C and either 45 °C or 65 °C.

Unconditioned

Temperature (C) Conductivity Mean (W/m-K) Standard Deviation (W/m-K)
15.0 0.124 0.003
45.0 0.134 0.003

Dried

Temperature (C) Conductivity Mean (W/m-K) Standard Deviation (W/m-K)
15.0 0.111 0.001
45.0 0.117 0.001

Mass Loss Rate (MLR)

Initial-mass-normalized mass loss rate [1/s] was measured in the simultaneous thermal analyzer experiments at three heating rates: 3 K/min, 10 K/min, and 30 K/min and mass loss rate [g/s] in the cone calorimeter at three heat fluxes: 25 kW/m2, 50 kW/m2, and 75 kW/m2.

Cone Calorimeter Test Notes:
This material warps and shrinks during cone calorimeter tests. Warping was observed in the first test (HF25_R1) and prevented in all subsequent tests by the use of tie wires. The sample self-extinguished in one test, HF25_R3, and reignited after the spark ignitor was inserted. Representative test pictures are available at the link above to Download raw data.

Simultaneous Thermal Analyzer

Cone Calorimeter: 25 kW/m2

Cone Calorimeter: 50 kW/m2

Cone Calorimeter: 75 kW/m2

Heat Release Rate Per Unit Area (HRRPUA)

Experiments for heat release per unit area [kW/m2] were conducted on samples conditioned at 20°C and 50% relative humidity using a cone calorimeter at three different heat fluxes: 25 kW/m2, 50 kW/m2, and 75 kW/m2.

This material warps and shrinks during cone calorimeter tests. Warping was observed in the first test (HF25_R1) and prevented in all subsequent tests by the use of tie wires. The sample self-extinguished in one test, HF25_R3, and reignited after the spark ignitor was inserted. Representative test pictures are available at the link above to Download raw data.

Cone Calorimeter: 25 kW/m2

25 kW/m² R1 25 kW/m² R2 25 kW/m² R3 25 kW/m² R4
Time to Sustained Ignition (s) 138.50 150.50 147.50 140.50
Time to Peak HRRPUA (s) 34.50 44.25 1418.00 48.25
Peak HRRPUA (kW/m²) 240.34 191.44 219.44 196.47

Cone Calorimeter: 50 kW/m2

50 kW/m² R1 50 kW/m² R2 50 kW/m² R3
Time to Sustained Ignition (s) 35.75 31.75 33.25
Time to Peak HRRPUA (s) 44.25 42.50 49.75
Peak HRRPUA (kW/m²) 317.46 317.77 313.24

Cone Calorimeter: 75 kW/m2

75 kW/m² R1 75 kW/m² R2 75 kW/m² R3
Time to Sustained Ignition (s) 15.50 14.50 15.75
Time to Peak HRRPUA (s) 40.25 41.75 35.25
Peak HRRPUA (kW/m²) 452.25 438.62 436.68

Carbon Monoxide (CO) Yield

Carbon monoxide yield was measured during cone calorimeter experiments conducted at heat fluxes of 25 kW/m2, 50 kW/m2, and 75 kW/m2.

This material warps and shrinks during cone calorimeter tests. Warping was observed in the first test (HF25_R1) and prevented in all subsequent tests by the use of tie wires. The sample self-extinguished in one test, HF25_R3, and reignited after the spark ignitor was inserted. Representative test pictures are available at the link above to Download raw data.

Incident Heat Flux [kW/m²] Mean CO Yield [g/g] CO Yield Std. Dev. [g/g]
25 0.027 0.003
50 0.006 0.0
75 0.006 0.0

Specific Heat Release Rate

Experiments for specific heat release rate [W/g], were conducted using a micro-scale combustion calorimeter at a heating rate of 30 K/min.

Derived Data

Effective Heat of Combustion (Δhc)

Effective heat of combustion [MJ/kg] is calculated from data collected in micro-scale combustion calorimeter experiments.

Micro-scale Combustion Calorimeter

Value R1 R3 R4 Mean Std. Dev.
Heat of Combustion (MJ/kg) 12.6 11.54 11.19 11.78 0.6

Temperature at Onset of Decomposition

The temperature at onset of decomposition [Tonset] is a derived quantity computed from data collected in simultaneous thermal analyzer experiments.

3 °C/min 10 °C/min 30 °C/min
Mean Onset Temperature (°C) 188 198 212
Std. Dev. Onset Temperature (°C) NaN 3 4
Mean Normalized MLR at Onset (1/s) 4.40e-04 4.24e-04 4.56e-04
Std. Dev. Normalized MLR at Onset (1/s) NaN 0.09e-04 0.59e-04
Mean Mass Fraction at Onset 0.98 0.98 0.98
Std. Dev. Mass Fraction at Onset NaN 0.00 0.00
Mean Temperature at end of Decomposition (°C) 448 447 463
Std. Dev. Temperature at end of Decomposition (°C) NaN 21 18

Band Averaged Emissivity

Band averaged emissivity was calculated from reflectance measurements conducted with an integrating sphere and Fourier transform infrared spectrometer.

Source Temperature [K] Emissivity Std. Dev.
600.0 0.929 0.001
800.0 0.902 0.002
1000.0 0.866 0.004
1200.0 0.827 0.007
1400.0 0.791 0.010
1600.0 0.759 0.013
1800.0 0.732 0.015
2000.0 0.710 0.018