Measured Data

Specific Heat

Experiments for specific heat [J/(kg K)], or heat capacity, were conducted using a heat flow meter on unconditioned and dried samples at 10 °C, 20 °C, 30 °C and 40 °C.

Unconditioned

Temperature (C) Specific Heat Mean (J/kg-K) Standard Deviation (J/kg-K)
10.0 1143.0 NaN
20.0 1204.0 NaN
30.0 1288.0 NaN
40.0 1283.0 NaN

Thermal Conductivity

Experiments for thermal conductivity [W/(m K)] were conducted using a heat flow meter on unconditioned and dried samples at 15 °C and either 45 °C or 65 °C.

Unconditioned

Temperature (C) Conductivity Mean (W/m-K) Standard Deviation (W/m-K)
30.0 0.118 0.001
35.0 0.120 0.001
40.0 0.122 0.001
45.0 0.123 0.001

Dried

Temperature (C) Conductivity Mean (W/m-K) Standard Deviation (W/m-K)
30.0 0.107 0.0
35.0 NaN NaN
40.0 NaN NaN
45.0 0.110 0.0

Mass Loss Rate (MLR)

Initial-mass-normalized mass loss rate [1/s] was measured in the simultaneous thermal analyzer experiments at three heating rates: 3 K/min, 10 K/min, and 30 K/min and mass loss rate [g/s] in the cone calorimeter at three heat fluxes: 25 kW/m2, 50 kW/m2, and 75 kW/m2.

Simultaneous Thermal Analyzer

Cone Calorimeter: 25 kW/m2

Cone Calorimeter: 50 kW/m2

Cone Calorimeter: 75 kW/m2

Heat Release Rate Per Unit Area (HRRPUA)

Experiments for heat release per unit area [kW/m2] were conducted on samples conditioned at 20°C and 50% relative humidity using a cone calorimeter at three different heat fluxes: 25 kW/m2, 50 kW/m2, and 75 kW/m2.

Cone Calorimeter: 25 kW/m2

25 kW/m² R1 25 kW/m² R2 25 kW/m² R3
Time to Sustained Ignition (s) 136.75 148.75 136.75
Time to Peak HRRPUA (s) 1112.75 1106.50 1088.25
Peak HRRPUA (kW/m²) 264.58 254.28 262.60

Cone Calorimeter: 50 kW/m2

50 kW/m² R1 50 kW/m² R2 50 kW/m² R3
Time to Sustained Ignition (s) 31.00 31.75 30.25
Time to Peak HRRPUA (s) 18.00 17.75 1049.25
Peak HRRPUA (kW/m²) 345.89 329.34 372.96

Cone Calorimeter: 75 kW/m2

75 kW/m² R1 75 kW/m² R2 75 kW/m² R3
Time to Sustained Ignition (s) 16.25 13.75 14.50
Time to Peak HRRPUA (s) 24.75 21.50 24.75
Peak HRRPUA (kW/m²) 420.47 433.95 430.87

Carbon Monoxide (CO) Yield

Carbon monoxide yield was measured during cone calorimeter experiments conducted at heat fluxes of 25 kW/m2, 50 kW/m2, and 75 kW/m2.

Incident Heat Flux [kW/m²] Mean CO Yield [g/g] CO Yield Std. Dev. [g/g]
25 0.009 0.0
50 0.003 0.0
75 0.007 0.0

Specific Heat Release Rate

Experiments for specific heat release rate [W/g], were conducted using a micro-scale combustion calorimeter at a heating rate of 30 K/min.

Derived Data

Effective Heat of Combustion (Δhc)

Effective heat of combustion [MJ/kg] is calculated from data collected in micro-scale combustion calorimeter experiments.

Micro-scale Combustion Calorimeter

Value R1 R2 R3 Mean Std. Dev.
Heat of Combustion (MJ/kg) 12.88 13.18 14.01 13.36 0.48

Temperature at Onset of Decomposition

The temperature at onset of decomposition [Tonset] is a derived quantity computed from data collected in simultaneous thermal analyzer experiments.

3 °C/min 10 °C/min 30 °C/min
Mean Onset Temperature (°C) 219 227 244
Std. Dev. Onset Temperature (°C) 9 5 5
Mean Normalized MLR at Onset (1/s) 6.51e-04 4.64e-04 4.76e-04
Std. Dev. Normalized MLR at Onset (1/s) 1.86e-04 0.12e-04 0.60e-04
Mean Mass Fraction at Onset 0.98 0.98 0.98
Std. Dev. Mass Fraction at Onset 0.00 0.00 0.00
Mean Temperature at end of Decomposition (°C) 428 457 478
Std. Dev. Temperature at end of Decomposition (°C) 8 12 5