Measured Data
Specific Heat
Experiments for specific heat [J/(kg K)], or heat capacity, were conducted using a heat flow meter on unconditioned and dried samples at 10 °C, 20 °C, 30 °C and 40 °C.
Unconditioned
| Temperature (C) | Specific Heat Mean (J/kg-K) | Standard Deviation (J/kg-K) |
|---|---|---|
| 10.0 | 1268.0 | 510.0 |
| 20.0 | 1314.0 | 535.0 |
| 30.0 | 1363.0 | 648.0 |
| 40.0 | 1451.0 | 601.0 |
Dried
| Temperature (C) | Specific Heat Mean (J/kg-K) | Standard Deviation (J/kg-K) |
|---|---|---|
| 10.0 | 1220.0 | 209.0 |
| 20.0 | 1273.0 | 225.0 |
| 30.0 | 1320.0 | 239.0 |
| 40.0 | 1349.0 | 278.0 |
Thermal Conductivity
Experiments for thermal conductivity [W/(m K)] were conducted using a heat flow meter on unconditioned and dried samples at 15 °C and either 45 °C or 65 °C.
Unconditioned
| Temperature (C) | Conductivity Mean (W/m-K) | Standard Deviation (W/m-K) |
|---|---|---|
| 15.0 | 0.023 | 0.003 |
| 65.0 | 0.028 | 0.003 |
Dried
| Temperature (C) | Conductivity Mean (W/m-K) | Standard Deviation (W/m-K) |
|---|---|---|
| 15.0 | 0.020 | 0.003 |
| 65.0 | 0.025 | 0.003 |
Mass Loss Rate (MLR)
Initial-mass-normalized mass loss rate [1/s] was measured in the simultaneous thermal analyzer experiments at three heating rates: 3 K/min, 10 K/min, and 30 K/min and mass loss rate [g/s] in the cone calorimeter at three heat fluxes: 25 kW/m2, 50 kW/m2, and 75 kW/m2.
Cone Calorimeter Test Notes:
This material shrivels under thermal exposure which reduces the exposed surface area during cone calorimeter tests. An edge frame was used to limit this behavior. A calcium silicate substrate was included beneath the samples.
Simultaneous Thermal Analyzer
Cone Calorimeter: 25 kW/m2
Cone Calorimeter: 50 kW/m2
Cone Calorimeter: 75 kW/m2
Heat Release Rate Per Unit Area (HRRPUA)
Experiments for heat release per unit area [kW/m2] were conducted on samples conditioned at 20°C and 50% relative humidity using a cone calorimeter at three different heat fluxes: 25 kW/m2, 50 kW/m2, and 75 kW/m2.
This material shrivels under thermal exposure which reduces the exposed surface area during cone calorimeter tests. An edge frame was used to limit this behavior. A calcium silicate substrate was included beneath the samples.
Cone Calorimeter: 25 kW/m2
| 25 kW/m² R1 | 25 kW/m² R2 | 25 kW/m² R3 | |
|---|---|---|---|
| Time to Sustained Ignition (s) | 8.75 | 10.75 | 9.75 |
| Time to Peak HRRPUA (s) | 7.25 | 6.25 | 7.00 |
| Peak HRRPUA (kW/m²) | 174.18 | 170.22 | 174.17 |
Cone Calorimeter: 50 kW/m2
| 50 kW/m² R1 | 50 kW/m² R2 | 50 kW/m² R3 | |
|---|---|---|---|
| Time to Sustained Ignition (s) | 2.75 | 3.00 | 3.25 |
| Time to Peak HRRPUA (s) | 3.75 | 4.25 | 4.25 |
| Peak HRRPUA (kW/m²) | 190.75 | 188.64 | 211.42 |
Cone Calorimeter: 75 kW/m2
| 75 kW/m² R1 | 75 kW/m² R2 | 75 kW/m² R3 | |
|---|---|---|---|
| Time to Sustained Ignition (s) | 2.00 | 2.25 | 1.75 |
| Time to Peak HRRPUA (s) | 3.75 | 3.00 | 4.00 |
| Peak HRRPUA (kW/m²) | 221.88 | 238.17 | 191.20 |
Carbon Monoxide (CO) Yield
Carbon monoxide yield was measured during cone calorimeter experiments conducted at heat fluxes of 25 kW/m2, 50 kW/m2, and 75 kW/m2.
This material shrivels under thermal exposure which reduces the exposed surface area during cone calorimeter tests. An edge frame was used to limit this behavior. A calcium silicate substrate was included beneath the samples.
| Incident Heat Flux [kW/m²] | Mean CO Yield [g/g] | CO Yield Std. Dev. [g/g] |
|---|---|---|
| 25 | 0.005 | 0.002 |
| 50 | 0.004 | 0.002 |
| 75 | 0.006 | 0.004 |
Specific Heat Release Rate
Experiments for specific heat release rate [W/g], were conducted using a micro-scale combustion calorimeter at a heating rate of 30 K/min.
Derived Data
Effective Heat of Combustion (Δhc)
Effective heat of combustion [MJ/kg] is calculated from data collected in micro-scale combustion calorimeter experiments.
Micro-scale Combustion Calorimeter
| Value | R1 | R2 | R3 | Mean | Std. Dev. |
|---|---|---|---|---|---|
| Heat of Combustion (MJ/kg) | 13.55 | 12.98 | 13.22 | 13.25 | 0.23 |
Temperature at Onset of Decomposition
The temperature at onset of decomposition [Tonset] is a derived quantity computed from data collected in simultaneous thermal analyzer experiments.
| 10 °C/min | |
|---|---|
| Mean Onset Temperature (°C) | 292 |
| Std. Dev. Onset Temperature (°C) | 0 |
| Mean Normalized MLR at Onset (1/s) | 9.37e-04 |
| Std. Dev. Normalized MLR at Onset (1/s) | 0.10e-04 |
| Mean Mass Fraction at Onset | 0.97 |
| Std. Dev. Mass Fraction at Onset | 0.00 |
| Mean Temperature at end of Decomposition (°C) | 387 |
| Std. Dev. Temperature at end of Decomposition (°C) | 0 |
Band Averaged Emissivity
Band averaged emissivity was calculated from reflectance measurements conducted with an integrating sphere and Fourier transform infrared spectrometer.
| Source Temperature [K] | Emissivity | Std. Dev. |
|---|---|---|
| 600.0 | 0.858 | 0.003 |
| 800.0 | 0.826 | 0.004 |
| 1000.0 | 0.790 | 0.006 |
| 1200.0 | 0.752 | 0.008 |
| 1400.0 | 0.717 | 0.011 |
| 1600.0 | 0.688 | 0.013 |
| 1800.0 | 0.664 | 0.015 |
| 2000.0 | 0.644 | 0.017 |