Measured Data

Specific Heat

Experiments for specific heat [J/(kg K)], or heat capacity, were conducted using a heat flow meter on unconditioned and dried samples at 10 °C, 20 °C, 30 °C and 40 °C.

Unconditioned

Temperature (C) Specific Heat Mean (J/kg-K) Standard Deviation (J/kg-K)
10.0 1268.0 510.0
20.0 1314.0 535.0
30.0 1363.0 648.0
40.0 1451.0 601.0

Dried

Temperature (C) Specific Heat Mean (J/kg-K) Standard Deviation (J/kg-K)
10.0 1220.0 209.0
20.0 1273.0 225.0
30.0 1320.0 239.0
40.0 1349.0 278.0

Thermal Conductivity

Experiments for thermal conductivity [W/(m K)] were conducted using a heat flow meter on unconditioned and dried samples at 15 °C and either 45 °C or 65 °C.

Unconditioned

Temperature (C) Conductivity Mean (W/m-K) Standard Deviation (W/m-K)
15.0 0.023 0.003
65.0 0.028 0.003

Dried

Temperature (C) Conductivity Mean (W/m-K) Standard Deviation (W/m-K)
15.0 0.020 0.003
65.0 0.025 0.003

Mass Loss Rate (MLR)

Initial-mass-normalized mass loss rate [1/s] was measured in the simultaneous thermal analyzer experiments at three heating rates: 3 K/min, 10 K/min, and 30 K/min and mass loss rate [g/s] in the cone calorimeter at three heat fluxes: 25 kW/m2, 50 kW/m2, and 75 kW/m2.

Cone Calorimeter Test Notes:
This material shrivels under thermal exposure which reduces the exposed surface area during cone calorimeter tests. An edge frame was used to limit this behavior. A calcium silicate substrate was included beneath the samples.

Simultaneous Thermal Analyzer

Cone Calorimeter: 25 kW/m2

Cone Calorimeter: 50 kW/m2

Cone Calorimeter: 75 kW/m2

Heat Release Rate Per Unit Area (HRRPUA)

Experiments for heat release per unit area [kW/m2] were conducted on samples conditioned at 20°C and 50% relative humidity using a cone calorimeter at three different heat fluxes: 25 kW/m2, 50 kW/m2, and 75 kW/m2.

This material shrivels under thermal exposure which reduces the exposed surface area during cone calorimeter tests. An edge frame was used to limit this behavior. A calcium silicate substrate was included beneath the samples.

Cone Calorimeter: 25 kW/m2

25 kW/m² R1 25 kW/m² R2 25 kW/m² R3
Time to Sustained Ignition (s) 8.75 10.75 9.75
Time to Peak HRRPUA (s) 7.25 6.25 7.00
Peak HRRPUA (kW/m²) 174.18 170.22 174.17

Cone Calorimeter: 50 kW/m2

50 kW/m² R1 50 kW/m² R2 50 kW/m² R3
Time to Sustained Ignition (s) 2.75 3.00 3.25
Time to Peak HRRPUA (s) 3.75 4.25 4.25
Peak HRRPUA (kW/m²) 190.75 188.64 211.42

Cone Calorimeter: 75 kW/m2

75 kW/m² R1 75 kW/m² R2 75 kW/m² R3
Time to Sustained Ignition (s) 2.00 2.25 1.75
Time to Peak HRRPUA (s) 3.75 3.00 4.00
Peak HRRPUA (kW/m²) 221.88 238.17 191.20

Carbon Monoxide (CO) Yield

Carbon monoxide yield was measured during cone calorimeter experiments conducted at heat fluxes of 25 kW/m2, 50 kW/m2, and 75 kW/m2.

This material shrivels under thermal exposure which reduces the exposed surface area during cone calorimeter tests. An edge frame was used to limit this behavior. A calcium silicate substrate was included beneath the samples.

Incident Heat Flux [kW/m²] Mean CO Yield [g/g] CO Yield Std. Dev. [g/g]
25 0.005 0.002
50 0.004 0.002
75 0.006 0.004

Specific Heat Release Rate

Experiments for specific heat release rate [W/g], were conducted using a micro-scale combustion calorimeter at a heating rate of 30 K/min.

Derived Data

Effective Heat of Combustion (Δhc)

Effective heat of combustion [MJ/kg] is calculated from data collected in micro-scale combustion calorimeter experiments.

Micro-scale Combustion Calorimeter

Value R1 R2 R3 Mean Std. Dev.
Heat of Combustion (MJ/kg) 13.55 12.98 13.22 13.25 0.23

Temperature at Onset of Decomposition

The temperature at onset of decomposition [Tonset] is a derived quantity computed from data collected in simultaneous thermal analyzer experiments.

10 °C/min
Mean Onset Temperature (°C) 292
Std. Dev. Onset Temperature (°C) 0
Mean Normalized MLR at Onset (1/s) 9.37e-04
Std. Dev. Normalized MLR at Onset (1/s) 0.10e-04
Mean Mass Fraction at Onset 0.97
Std. Dev. Mass Fraction at Onset 0.00
Mean Temperature at end of Decomposition (°C) 387
Std. Dev. Temperature at end of Decomposition (°C) 0

Band Averaged Emissivity

Band averaged emissivity was calculated from reflectance measurements conducted with an integrating sphere and Fourier transform infrared spectrometer.

Source Temperature [K] Emissivity Std. Dev.
600.0 0.858 0.003
800.0 0.826 0.004
1000.0 0.790 0.006
1200.0 0.752 0.008
1400.0 0.717 0.011
1600.0 0.688 0.013
1800.0 0.664 0.015
2000.0 0.644 0.017