Measured Data

Heat Release Rate Per Unit Area (HRRPUA)

Experiments for heat release per unit area [kW/m2] were conducted on samples conditioned at 20°C and 50% relative humidity using a cone calorimeter at three different heat fluxes: 25 kW/m2, 50 kW/m2, and 75 kW/m2.

Samples were tested without compression of the material. The sample preparation consisted of filling a pre-formed, 5 cm deep aluminum foil tray with cellulose insulation, and attempting to achieve homogenous packing density. At the 50 kW/m2 and 75 kW/m2 exposures, ignition occurred in less than 1 second -- faster than the recorded time.

Cone Calorimeter: 25 kW/m2

25 kW/m² R1 25 kW/m² R2 25 kW/m² R3
Time to Sustained Ignition (s) 9.75 12.00 9.25
Time to Peak HRRPUA (s) 19.50 19.25 18.75
Peak HRRPUA (kW/m²) 121.37 135.28 121.11

Cone Calorimeter: 50 kW/m2

50 kW/m² R1 50 kW/m² R2 50 kW/m² R3
Time to Sustained Ignition (s) 2.25 1.25 1.50
Time to Peak HRRPUA (s) 21.25 21.50 21.50
Peak HRRPUA (kW/m²) 177.26 195.73 184.22

Cone Calorimeter: 75 kW/m2

75 kW/m² R1 75 kW/m² R2 75 kW/m² R3
Time to Sustained Ignition (s) 1.75 2.00 1.50
Time to Peak HRRPUA (s) 19.25 19.50 18.75
Peak HRRPUA (kW/m²) 273.02 271.94 258.88

Mass Loss Rate (MLR)

Initial-mass-normalized mass loss rate [1/s] was measured in the simultaneous thermal analyzer experiments at three heating rates: 3 K/min, 10 K/min, and 30 K/min and mass loss rate [g/s] in the cone calorimeter at three heat fluxes: 25 kW/m2, 50 kW/m2, and 75 kW/m2.

Cone Calorimeter Test Notes:
Samples were tested without compression of the material. The sample preparation consisted of filling a pre-formed, 5 cm deep aluminum foil tray with cellulose insulation, and attempting to achieve homogenous packing density. At the 50 kW/m2 and 75 kW/m2 exposures, ignition occurred in less than 1 second -- faster than the recorded time.

Simultaneous Thermal Analyzer

Cone Calorimeter: 25 kW/m2

Cone Calorimeter: 50 kW/m2

Cone Calorimeter: 75 kW/m2

Specific Heat

Experiments for specific heat [J/(kg K)], or heat capacity, were conducted using a heat flow meter on unconditioned and dried samples at 10 °C, 20 °C, 30 °C and 40 °C.

Unconditioned

Temperature (C) Specific Heat Mean (J/kg-K) Standard Deviation (J/kg-K)
10.0 1533.0 366.0
20.0 1598.0 388.0
30.0 1674.0 403.0
40.0 1741.0 417.0

Thermal Conductivity

Experiments for thermal conductivity [k] were conducted using a heat flow meter on unconditioned samples at 15 °C and 45 °C.

Unconditioned

Temperature (C) Conductivity Mean (W/m-K) Standard Deviation (W/m-K)
15.0 0.045 0.001
45.0 0.050 0.001

Carbon Monoxide (CO) Yield

Carbon monoxide yield was measured during cone calorimeter experiments conducted at heat fluxes of 25 kW/m2, 50 kW/m2, and 75 kW/m2.

Samples were tested without compression of the material. The sample preparation consisted of filling a pre-formed, 5 cm deep aluminum foil tray with cellulose insulation, and attempting to achieve homogenous packing density. At the 50 kW/m2 and 75 kW/m2 exposures, ignition occurred in less than 1 second -- faster than the recorded time.

Incident Heat Flux [kW/m²] Mean CO Yield [g/g] CO Yield Std. Dev. [g/g]
25 0.047 0.027
50 0.026 0.002
75 0.009 0.002

Specific Heat Release Rate

Experiments for specific heat release rate [W/g], were conducted using a micro-scale combustion calorimeter at a heating rate of 30 K/min.

Derived Data

Effective Heat of Combustion (Δhc)

Effective heat of combustion [MJ/kg] is calculated from data collected in micro-scale combustion calorimeter experiments.

Micro-scale Combustion Calorimeter

Value R1 R2 R3 Mean Std. Dev.
Heat of Combustion (MJ/kg) 6.7 5.79 6.29 6.26 0.37

Temperature at Onset of Decomposition

The temperature at onset of decomposition [Tonset] is a derived quantity computed from data collected in simultaneous thermal analyzer experiments.

10 °C/min
Mean Onset Temperature (°C) 167
Std. Dev. Onset Temperature (°C) 20
Mean Normalized MLR at Onset (1/s) 3.88e-04
Std. Dev. Normalized MLR at Onset (1/s) 0.02e-04
Mean Mass Fraction at Onset 0.96
Std. Dev. Mass Fraction at Onset 0.01
Mean Temperature at end of Decomposition (°C) 490
Std. Dev. Temperature at end of Decomposition (°C) 6

Band Averaged Emissivity

Band averaged emissivity was calculated from reflectance measurements conducted with an integrating sphere and Fourier transform infrared spectrometer.

Source Temperature [K] Emissivity Std. Dev.
600.0 0.889 0.002
800.0 0.855 0.003
1000.0 0.819 0.005
1200.0 0.783 0.007
1400.0 0.751 0.010
1600.0 0.724 0.012
1800.0 0.702 0.015
2000.0 0.685 0.017